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Coulomb wave function : ウィキペディア英語版
Coulomb wave function
In mathematics, a Coulomb wave function is a solution of the Coulomb wave equation, named after Charles-Augustin de Coulomb. They are used to describe the behavior of charged particles in a Coulomb potential and can be written in terms of confluent hypergeometric functions or Whittaker functions of imaginary argument.
==Coulomb wave equation==
The Coulomb wave equation for a single charged particle is the Schrödinger equation with Coulomb potential
:\left(-\frac+\frac\right) \psi_) = \frac \psi_) \,,
where Z=Z_1 Z_2 is the product of the charges of the particle and of the field source (in units of the elementary charge, Z=-1 for hydrogen atom) and k^2 is proportional to the asymptotic energy of the particle. The solution – Coulomb wave function – can be found by solving this equation in parabolic coordinates
:\xi= r + \vec\cdot\hat, \quad \zeta= r - \vec\cdot\hat \qquad (\hat = \vec/k) \,.
Depending on the boundary conditions chosen the solution has different forms. Two of the solutions are
:\psi_(\vec) = \frac e^} M(\mp i\eta, 1, \pm ikr - i\vec\cdot\vec) \,,
where M(a,b,z) \equiv (\vec) \rightarrow \frac\cdot\vec} \qquad (\vec\cdot\vec \rightarrow \mp\infty) \,,
which correspond to \vec-oriented plane-wave asymptotic state ''before'' or ''after'' its approach of the field source at the origin, respectively. The functions \psi_ are related to each other by the formula
:\psi_ = \psi_ \,.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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